Perodox 121: tert-Amyl peroxy-2-ethylhexanoate (686-31-7) — Polymerization Initiator for Polymer Production

August 12, 2026 3 min read

Versatile peroxyester with broad processing temperature range. Compatible with multiple monomer systems for copolymer production.

Quick Facts

Trade Name Perodox 121
Chemical Name tert-Amyl peroxy-2-ethylhexanoate
CAS Number 686-31-7
Chemical Family Ester Peroxide
Brand Perodox
Function Category Polymerization Initiator
Product Line Organic Peroxides – Ester Peroxides
Applications Copolymers, Multi-Monomer Systems
Market Segment Polymer Production
Physical Form Liquid
Decomposition Temperature 80-100°C
Active Oxygen Content
Molecular Weight

What Is tert-Amyl peroxy-2-ethylhexanoate?

tert-Amyl peroxy-2-ethylhexanoate is a ester peroxide supplied under the Perodox brand as part of the
Organic Peroxides – Ester Peroxides portfolio. Versatile peroxyester with broad processing temperature range. Compatible with multiple monomer systems for copolymer production. As a polymerization initiator,
it is engineered for demanding Polymer Production applications where consistency and purity are critical.

Key Properties & Specifications

  • Chemical family: Ester Peroxide
  • CAS number: 686-31-7
  • Physical form: Liquid
  • Decomposition temperature: 80-100°C
  • Active oxygen content:
  • Molecular weight:

How It Works

As an organic peroxide, tert-Amyl peroxy-2-ethylhexanoate decomposes by homolytic cleavage when heated near 80-100°C, generating free radicals. These radicals initiate the polymerization or crosslinking of unsaturated monomers (such as styrene, acrylates, vinyls and unsaturated polyester resins), making it a core radical initiator for thermoset and polymer manufacturing.

Primary Applications

Perodox 121 is applied across Copolymers, Multi-Monomer Systems. Typical market segments include Polymer Production.
Its performance profile makes it a trusted choice for formulators who need reproducible,
high-purity raw materials.

Safety, Handling & Storage

Handle Perodox 121 in accordance with its Safety Data Sheet (SDS). Store in original,
sealed packaging away from heat, ignition sources and incompatible materials, within the
recommended temperature range. Personal protective equipment and adequate ventilation are
required. Always consult the current SDS and applicable local regulations before use.

Regulatory & Compliance

Do Sender Chem supplies tert-Amyl peroxy-2-ethylhexanoate with full documentation and supports compliance with
international chemical regulations (including REACH where applicable). For controlled
precursor grades, supply is managed under know-your-customer and licensing procedures.

Why Source Perodox 121 from Do Sender Chem?

Do Sender Chem is a global specialty chemical manufacturer offering a broad, multi-language
catalog, consistent quality and responsive technical support. With localized content in 20
languages and worldwide delivery, we help polymer, rubber and specialty producers secure
reliable polymerization initiator supply.

Frequently Asked Questions

What is tert-Amyl peroxy-2-ethylhexanoate used for?

tert-Amyl peroxy-2-ethylhexanoate (trade name Perodox 121) is used as a Polymerization Initiator in Copolymers, Multi-Monomer Systems. It serves manufacturers in the Polymer Production segments.

What is the CAS number of tert-Amyl peroxy-2-ethylhexanoate?

The CAS Registry Number of tert-Amyl peroxy-2-ethylhexanoate is 686-31-7. The CAS number uniquely identifies the substance and is the standard reference used in safety data sheets, regulatory filings and procurement specifications.

Is tert-Amyl peroxy-2-ethylhexanoate classified as Ester Peroxide?

Yes. tert-Amyl peroxy-2-ethylhexanoate belongs to the Ester Peroxide chemical family and is marketed under the Perodox brand as part of the Organic Peroxides – Ester Peroxides product line.

How should Perodox 121 be stored and handled?

Perodox 121 should be stored according to its safety data sheet, away from heat, ignition sources and incompatible materials, in original sealed packaging under the recommended temperature range. Always consult the current SDS and local regulations before handling.

Which industries buy Perodox 121?

Perodox 121 is supplied to producers in the Polymer Production industries that require reliable, high-purity Polymerization Initiator raw materials.

Related Products

Explore other ester peroxide and polymerization initiator products in our catalog, or contact
our team for formulation guidance.

References

  • CAS Registry Number: 686-31-7 — tert-Amyl peroxy-2-ethylhexanoate
  • Do Sender Chem product data sheet: Perodox 121

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