Perodox B: Di-tert-butyl peroxide (DTBP) (110-05-4) — Polymerization Initiator, Crosslinking Agent for Polymer Production, Rubber and Elastomers

August 12, 2026 4 min read

High-temperature dialkyl peroxide initiator for acrylic resin polymerization and polyolefin crosslinking. Exceptional thermal stability with decomposition range 130-175°C.

Quick Facts

Trade Name Perodox B
Chemical Name Di-tert-butyl peroxide (DTBP)
CAS Number 110-05-4
Chemical Family Alkyl Peroxide
Brand Perodox
Function Category Polymerization Initiator, Crosslinking Agent
Product Line Organic Peroxides – Alkyl Peroxides
Applications Acrylic Resin, PP, LDPE, EVA, Rubber Crosslinking
Market Segment Polymer Production, Rubber and Elastomers
Physical Form Liquid
Decomposition Temperature 130-175°C
Active Oxygen Content 10.9%
Molecular Weight 146.23

What Is Di-tert-butyl peroxide (DTBP)?

Di-tert-butyl peroxide (DTBP) is a alkyl peroxide supplied under the Perodox brand as part of the
Organic Peroxides – Alkyl Peroxides portfolio. High-temperature dialkyl peroxide initiator for acrylic resin polymerization and polyolefin crosslinking. Exceptional thermal stability with decomposition range 130-175°C. As a polymerization initiator, crosslinking agent,
it is engineered for demanding Polymer Production, Rubber and Elastomers applications where consistency and purity are critical.

Key Properties & Specifications

  • Chemical family: Alkyl Peroxide
  • CAS number: 110-05-4
  • Physical form: Liquid
  • Decomposition temperature: 130-175°C
  • Active oxygen content: 10.9%
  • Molecular weight: 146.23

How It Works

As an organic peroxide, Di-tert-butyl peroxide (DTBP) decomposes by homolytic cleavage when heated near 130-175°C, generating free radicals. These radicals initiate the polymerization or crosslinking of unsaturated monomers (such as styrene, acrylates, vinyls and unsaturated polyester resins), making it a core radical initiator for thermoset and polymer manufacturing.

Primary Applications

Perodox B is applied across Acrylic Resin, PP, LDPE, EVA, Rubber Crosslinking. Typical market segments include Polymer Production, Rubber and Elastomers.
Its performance profile makes it a trusted choice for formulators who need reproducible,
high-purity raw materials.

Safety, Handling & Storage

Handle Perodox B in accordance with its Safety Data Sheet (SDS). Store in original,
sealed packaging away from heat, ignition sources and incompatible materials, within the
recommended temperature range. Personal protective equipment and adequate ventilation are
required. Always consult the current SDS and applicable local regulations before use.

Regulatory & Compliance

Do Sender Chem supplies Di-tert-butyl peroxide (DTBP) with full documentation and supports compliance with
international chemical regulations (including REACH where applicable). For controlled
precursor grades, supply is managed under know-your-customer and licensing procedures.

Why Source Perodox B from Do Sender Chem?

Do Sender Chem is a global specialty chemical manufacturer offering a broad, multi-language
catalog, consistent quality and responsive technical support. With localized content in 20
languages and worldwide delivery, we help polymer, rubber and specialty producers secure
reliable polymerization initiator, crosslinking agent supply.

Frequently Asked Questions

What is Di-tert-butyl peroxide (DTBP) used for?

Di-tert-butyl peroxide (DTBP) (trade name Perodox B) is used as a Polymerization Initiator, Crosslinking Agent in Acrylic Resin, PP, LDPE, EVA, Rubber Crosslinking. It serves manufacturers in the Polymer Production, Rubber and Elastomers segments.

What is the CAS number of Di-tert-butyl peroxide (DTBP)?

The CAS Registry Number of Di-tert-butyl peroxide (DTBP) is 110-05-4. The CAS number uniquely identifies the substance and is the standard reference used in safety data sheets, regulatory filings and procurement specifications.

Is Di-tert-butyl peroxide (DTBP) classified as Alkyl Peroxide?

Yes. Di-tert-butyl peroxide (DTBP) belongs to the Alkyl Peroxide chemical family and is marketed under the Perodox brand as part of the Organic Peroxides – Alkyl Peroxides product line.

How should Perodox B be stored and handled?

Perodox B should be stored according to its safety data sheet, away from heat, ignition sources and incompatible materials, in original sealed packaging under the recommended temperature range. Always consult the current SDS and local regulations before handling.

Which industries buy Perodox B?

Perodox B is supplied to producers in the Polymer Production, Rubber and Elastomers industries that require reliable, high-purity Polymerization Initiator, Crosslinking Agent raw materials.

Related Products

Explore other alkyl peroxide and polymerization initiator, crosslinking agent products in our catalog, or contact
our team for formulation guidance.

References

  • CAS Registry Number: 110-05-4 — Di-tert-butyl peroxide (DTBP)
  • Do Sender Chem product data sheet: Perodox B

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